Awesome Chemistry Experiments For 3939-23-9

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New banana shaped A?D?pi?D?A type organic dyes containing two anchoring groups for high performance dye-sensitized solar cells

Two new bent A?D?pi?D?A type organic dyes (MA-1 and MA-2) consisting of carbazole and phenothiazine moieties as electron donors with 2,1,3-benzothiadiazole as a pi-linker with two end-anchoring groups are designed, synthesized and tested in DSSCs. The photophysical and electrochemical properties of the dyes are investigated in detail. Incorporation of phenothiazine unit in MA-2 resulted in high HOMO level (0.62?V vs. NHE), with a red shift in absorption maxima and broadening of the absorption spectrum. Under standard global AM 1.5 solar conditions, the MA-2 sensitized solar cells exhibited a short circuit photocurrent density of 13.1?mA?cm?2, an open-circuit voltage of 0.73?V, a fill factor of 0.72, corresponding to an overall conversion efficiency of 6.87%. Such design and development of molecular dyes are useful for improving the overall efficiency of DSSCs.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

A new application about 3939-23-9

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The invention relates to a nitrogen-containing dibenz core six-membered heterocyclic ring of the compound and its in the organic electroluminescent device application (by machine translation)

The invention discloses a to dibenzofluorene and nitrogen-containing six-membered heterocyclic ring as the core of the compound and its in the organic electroluminescent device of the application. Compounds of the invention have higher glass transition temperature and molecular thermal stability, appropriate HOMO and LUMO energy level, higher Eg, through the device structural optimization, can effectively improve the OLED device of the service life of the photoelectric properties and OLED device, the compound structure such as formula (1) as shown: (by machine translation)

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

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The Extraction of Organic Bromo-compounds

The liquid extraction of organic bromo-compounds is discussed.The effect of the bromo-substituent on the partition coefficient depends on the activity of the extractant.The influence of the positions and numbers of bromine substituents on the partition coefficiemts is surveyed.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

Brief introduction of 3939-23-9

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Photochromic Radical Complexes That Show Heterolytic Bond Dissociation

Photochromic materials have been widely used in various research fields because of their variety of photoswitching properties based on various molecular frameworks and bond breaking processes, such as homolysis and heterolysis. However, while a number of photochromic molecular frameworks have been reported so far, there are few reports on photochromic molecular frameworks that show both homolysis and heterolysis depending on the substituents with high durability. The biradicals and zwitterions generated by homolysis and heterolysis have different physical and chemical properties and different potential applications. Therefore, the rational photochromic molecular design to control the bond dissociation in the excited state on demand expands the versatility for photoswitch materials beyond the conventional photochromic molecular frameworks. In this study, we synthesized novel photochromic molecules based on the framework of a radical-dissociation-type photochromic molecule: phenoxyl-imidazolyl radical complex (PIC). While the conventional PIC shows the photoinduced homolysis, the substitution of a strong electron-donating moiety to the phenoxyl moiety enables the bond dissociation process to be switched from homolysis to heterolysis. This study gives a strategy for controlling the bond dissociation process of the excited state of photochromic systems, and the strategy enables us to develop further novel radical and zwitterionic photoswitches.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

Extended knowledge of 3-Bromo-10H-phenothiazine

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Rearrangement of an aniline linked perylene bisimide under acidic conditions and visible to near-infrared emission from the intramolecular charge-transfer state of its fused derivatives

We have prepared a series of aniline-linked and fused perylene bisimides (PBIs) for making near-infrared (NIR) fluorophores. During this research, we found an unexpected rearrangement reaction on the PBI core for the first time. The aniline- and phenothiazine-fused PBIs exhibit excellent absorption ability and visible-to-NIR emission owing to their intramolecular charge transfer character.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

Brief introduction of 3939-23-9

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Chemistry can be defined as the study of matter and the changes it undergoes. Recommanded Product: 3-Bromo-10H-phenothiazine. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.3939-23-9, Name is 3-Bromo-10H-phenothiazine, molecular formula is C12H8BrNS, introducing its new discovery.

Spin-orbit charge transfer intersystem crossing in perylenemonoimide-phenothiazine compact electron donor-acceptor dyads

The spin-orbit charge transfer intersystem crossing (SOCT-ISC) of perylenemonoimide-phenothiazine compact dyads was shown to depend on the molecular geometry and the vector dipole orientations of the two chromophores, and the dyads show high triplet state quantum yields (57%).

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

More research is needed about 3-Bromo-10H-phenothiazine

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Spectroscopic investigations of vinyl-substituted 10H-phenothiazine

Different 10H-phenothiazine derivatives modified at their 3- and 3,7-positions with conjugated electron-deficient pyridine or pyridinium groups using ethenyl linkers are described. Spectral variations of 3-((E)-2-(Methylpyridium-4-yl)vinyl)-10H-phenothiazine iodide and 3,7-bis((E)-2-(Methylpyridium-4-yl)vinyl)-10H-phenothiazine diiodide, which are attributed to intramolecular charge transfer, electronic rearrangement and contact ion-pair mechanisms, were observed to be either base or ion dependent. Depending on the extent of deprotonation of the nitrogen atom in the 10-position of the phenothiazine core, donor-acceptor or push-pull systems provide fluorophore-switching and potential near infrared sensor application.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

Extended knowledge of 3-Bromo-10H-phenothiazine

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Potassium carbonate-mediated tandem C-S and C-N coupling reaction for the synthesis of phenothiazines under transition-metal-free and ligand-free conditions

An efficient potassium carbonate-mediated tandem C-S and C-N coupling reaction between N-(2-iodophenyl)acetamides and 2-halo-benzenethiols has been developed. This protocol affords a simple and efficient approach for the construction of phenothiazine derivatives without the need for addition of transition-metal catalyst or ligand for the first time. Furthermore, the reaction can be easily performed on a large scale.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

Some scientific research about 3939-23-9

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A heterocyclic compound and the use of the heterocyclic compounds of the organic light-emitting device (by machine translation)

The present invention provides a heterocyclic compound and the use of the heterocyclic compounds of the organic light-emitting device, which belongs to the technical field of organic photoelectric material. The invention heterocyclic compound, through increase wu group in the structure, obviously improves material hole transmission performance, by changing the connection of the group, can further improve its physical characteristics, thereby improving the characteristics of the organic light-emitting of the light emitting device. The use of the heterocyclic compounds as a hole transporting layer preparation organic light-emitting device, can be obtained with relatively low switching voltage and high luminous brightness, is an excellent OLED material. (by machine translation)

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

More research is needed about 3-Bromo-10H-phenothiazine

Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Recommanded Product: 3939-23-9, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 3939-23-9, in my other articles.

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Fluorescent organic nanoparticle formation in lysosomes for cancer cell recognition

We present a convenient method to prepare fluorophores 3- or 3,7-divinyl substituted 10H-phenothiazines and their protonation forms can aggregate to become fluorescent organic nanoparticles (FONs) with bright fluorescent spots in the lysosomes of cancer cells but not normal cells.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem