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Phenothiazinyl Boranes: A New Class of AIE Luminogens with Mega Stokes Shift, Mechanochromism, and Mechanoluminescence

Phenothiazines with a dimesityl boron moiety, a new class of aminoboranes with B?N linkage, were synthesized. These aminoboranes exhibited interesting photophysical behavior including aggregation-induced emission (AIE), mechanochromism (MC), mechanoluminescence (ML), and a mega Stokes shift (up to 312 nm in hexane). The solid-state emission of the aminoboranes could be switched reversibly by grinding?fuming processes. Furthermore, the phenothiazine derivative with a bromo and an arylborane group at 3- and 7-positions exhibited bright mechanoluminescence.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

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Photochromic Radical Complexes That Show Heterolytic Bond Dissociation

Photochromic materials have been widely used in various research fields because of their variety of photoswitching properties based on various molecular frameworks and bond breaking processes, such as homolysis and heterolysis. However, while a number of photochromic molecular frameworks have been reported so far, there are few reports on photochromic molecular frameworks that show both homolysis and heterolysis depending on the substituents with high durability. The biradicals and zwitterions generated by homolysis and heterolysis have different physical and chemical properties and different potential applications. Therefore, the rational photochromic molecular design to control the bond dissociation in the excited state on demand expands the versatility for photoswitch materials beyond the conventional photochromic molecular frameworks. In this study, we synthesized novel photochromic molecules based on the framework of a radical-dissociation-type photochromic molecule: phenoxyl-imidazolyl radical complex (PIC). While the conventional PIC shows the photoinduced homolysis, the substitution of a strong electron-donating moiety to the phenoxyl moiety enables the bond dissociation process to be switched from homolysis to heterolysis. This study gives a strategy for controlling the bond dissociation process of the excited state of photochromic systems, and the strategy enables us to develop further novel radical and zwitterionic photoswitches.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

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Fluorescent organic nanoparticle formation in lysosomes for cancer cell recognition

We present a convenient method to prepare fluorophores 3- or 3,7-divinyl substituted 10H-phenothiazines and their protonation forms can aggregate to become fluorescent organic nanoparticles (FONs) with bright fluorescent spots in the lysosomes of cancer cells but not normal cells.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

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Application of 3939-23-9, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 3939-23-9, 3-Bromo-10H-phenothiazine, introducing its new discovery.

Reaction of pi-Deficient Aromatic Heterocycles with Ammonium Polyhalides III [1]. Halogenation of Phenothiazin-5-oxide with Benzyltriethylammonium Polyhalides

Halogenation of phenothiazin-5-oxide with benzyltriethylammonium polyhalides (BTEA) under mild conditions afforded chloro- and bromophenothiazines as well as a few unexpected products e.g. 1,3,7,9-tetrachloro-phenothiazin-5-oxide, 7,3?-dibromo-3, 10?-diphenothiazinyl tribromide, and 7,3?-dichloro-3,10?-diphenothiazinyl tetrachloroiodate. A new charge-transfer complex of phenothiazine-5-oxide with bromine is reported.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

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3939-23-9, Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.3939-23-9, Name is 3-Bromo-10H-phenothiazine, molecular formula is C12H8BrNS, introducing its new discovery.

Fluorescent organic nanoparticle formation in lysosomes for cancer cell recognition

We present a convenient method to prepare fluorophores 3- or 3,7-divinyl substituted 10H-phenothiazines and their protonation forms can aggregate to become fluorescent organic nanoparticles (FONs) with bright fluorescent spots in the lysosomes of cancer cells but not normal cells.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

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13C Nuclear Magnetic Resonance of Some Derivatives of Phenothiazines, Pyridobenzothiazines and Phenoxazines

Natural abundance 13C NMR studies were carried out on a series of phenothiazines, pyridobenzothiazines and phenoxazines.Chemical shift assignments were made on the basis of models, coupling patterns and aromatic substituent affects.For most of the compounds studied, substituents influence only the carbon chemical shifts of the substituted carbocyclic ring, while the chemical shifts of the unsubstituted ring are essentially the same as those of the parent heterocyclic compound.However, the 10-acetyl and 4′-nitro-10-phenyl groups affect the chemical shifts of several of the carbon atoms in the phenothiazine nucleus.An explanation in terms of resonance interactions between these groups and the N-10 lone-pair electrons is presented.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

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Rearrangement of an aniline linked perylene bisimide under acidic conditions and visible to near-infrared emission from the intramolecular charge-transfer state of its fused derivatives

We have prepared a series of aniline-linked and fused perylene bisimides (PBIs) for making near-infrared (NIR) fluorophores. During this research, we found an unexpected rearrangement reaction on the PBI core for the first time. The aniline- and phenothiazine-fused PBIs exhibit excellent absorption ability and visible-to-NIR emission owing to their intramolecular charge transfer character.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.3939-23-9, Name is 3-Bromo-10H-phenothiazine, molecular formula is C12H8BrNS, 3939-23-9. In a Article, authors is Su, Sheng-Yuan£¬once mentioned of 3939-23-9

Dual optical responses of phenothiazine derivatives: Near-IR chromophore and water-soluble fluorescent organic nanoparticles

We have designed a conventional one-step organic coupling synthetic method to prepare a series of 10H-phenothiazine (PTZ) derivative fluorophores and investigated their optical behavior under alkaline conditions. The unexpected proton detachment at N-10 position (10N-H) of these PTZ derivatives provides switching between the visible fluorophore and near infrared (NIR) chromophore. Both anionic forms of compounds PTZ-NH and PTZ-OH exhibit strong red emission in alkali DMSO solutions, whereas only anionic PTZ-OH exhibits the near infrared absorption wavelength at 1010 nm. Moreover, the unexpected green fluorescence is observed due to the formation of fluorescent organic nanoparticles (FONs) when PTZ-OH is dissolved in alkaline aqueous conditions. These results indicate that these compounds have the potential for use in alkaline sensor applications, especially in aqueous solution.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

More research is needed about 3-Bromo-10H-phenothiazine

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.3939-23-9, Name is 3-Bromo-10H-phenothiazine, molecular formula is C12H8BrNS, 3939-23-9. In a Article, authors is Tan, Jingyun£¬once mentioned of 3939-23-9

Spiro[pyrrol-benzopyran]-based probe with high asymmetry for chiroptical sensing: Via circular dichroism

This contribution describes an efficient approach to constructing chiral spiro[pyrrol-benzopyran] (SPP) scaffold with high asymmetry. By combining chiral SPP and the achiral sensing moiety phenothiazine, the target probe P showed unprecedented reaction-based chiroptical sensing towards hypochlorite with switching CD signals.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem

 

Discovery of 3-Bromo-10H-phenothiazine

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The Extraction of Organic Bromo-compounds

The liquid extraction of organic bromo-compounds is discussed.The effect of the bromo-substituent on the partition coefficient depends on the activity of the extractant.The influence of the positions and numbers of bromine substituents on the partition coefficiemts is surveyed.

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Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem